You have to login with your ACS ID befor you can login with your Mendeley account. Get article recommendations from ACS based on references in your Mendeley library. Reduction par le zinc en presence d'acides—I. Find more information about Crossref citation counts. The Clemmensen reduction's original harsh conditions are not conducive to acid sensitive substrates so several modifications have been made to increase its synthetic utility by expanding the functional group tolerance. Note: You’ve supercharged your research process with ACS and Mendeley! The reaction conditions are highly acidic, therefore this reaction is used complementarily with the Wolff-Kishner reduction (which is done under basic conditions) and thioacetal desufurization (which is mediated by Raney nickel). A conjugate addition/dipolar-cycloaddition cascade sequence for the synthesis of (±)-cylindricine C. A Modified Clemmensen Reduction Procedure for Conversion of Aryl Ketones into Aryl Alkenes. You’ve supercharged your research process with ACS and Mendeley! Find more information about Crossref citation counts. Reductions at Metal Surfaces. Control of a reaction by TLC Supplementary Material This work is intended to first year chemistry students and uses the easily performed reduction of benzophenone to diphenylmethanol in the presence of sodium borohydride as a starting point to introduce the control of a reaction by TLC. These metrics are regularly updated to reflect usage leading up to the last few days. Please reconnect. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Evidence for the Formation of an Intermediate Carbonium Ion. Studies in the zinc reduction series: The reduction of certain 2-benzoylbenzoic acids and esters. II. 16 publications. This article is cited by Wepster. Studies in the zinc reduction series: Relationship of zinc and acid to zinc and alkali reductions of aldehydes and ketones. View Show abstract I. Elphimoff-Felkin, P. Sarda. Reuvers, H. van Bekkum, B.M. To learn about our use of cookies and how you can manage your cookie settings, please see our Cookie Policy. International Journal of Radiation Applications and Instrumentation. Andrew C. Flick, Maria José Arevalo Caballero, Albert Padwa. 1913, 46, 1837. Recueil des Travaux Chimiques des Pays-Bas. You have to login with your ACS ID befor you can login with your Mendeley account. 26, No. O. Häfliger, A. Brossi, L. H. Chopard-dit-Jean, M. Walter, O. Schnider. DOI: 10.1080/00397919608004578. Schwefel-Heterocyclen und Vorstufen, 59. Synthetic Communications 1996, 26 (14) , 2625-2631. A Modified Clemmensen Reduction Procedure for Conversion of Aryl Ketones into Aryl Alkenes. Registered in England & Wales No. G. E. Risinger, J. M. Garrett, J. The Clemmensen reduction of 2-acetylfluorene may proceed through the corresponding carbinol, 2-(α-hydroxyethyl)fluorene, to the normal reduction product, 2-ethylfluorene. Reduction of carbonyl compounds by Raney Ni–Al alloy and Al powder in the presence of noble metal catalysts in water. A Modified Clemmensen Reduction Procedure for Conversion of Aryl Ketones into Aryl Alkenes. Deuterium and tritium labeling of (3-xenyl)cyclohexane by Clemmensen and Wolff-Kishner reduction. In lieu of an abstract, this is the article's first page. 3099067 Reduction par le zinc en presence d'acides—I. Two-Step 1,2-Shifts by β-Cleavage of Carbenium Ions and Recombination in Friedel−Crafts Reactions of 2-tert-Butyl-1-tosylaziridines1. Der Mechanismus der Clemmensen-Reduktion. Die asymmetrische elektrochemische reduktion einiger alkyl-phenyl-ketone in gegenwart optisch aktiver leitsalze. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Clemmensen-Reduktion und Halbstufenpotentiale einiger Thiocarbonsäuren und Abkömmlinge. Deuterium and tritium labeling of (3-xenyl)cyclohexane by Clemmensen and Wolff-Kishner reduction. The well-known Clemmensen reduction 4 is a general method by which aralkyl ketones are readily converted to the corresponding hydrocarbons with amalgamated zinc and hydrochloric acid.It is not particularly effective, however, with alicyclic and aliphatic ketones. Reduction of a ketone using sodium borohydride. Register to receive personalised research and resources by email, An International Journal for Rapid Communication of Synthetic Organic Chemistry, A Modified Clemmensen Reduction Procedure for Conversion of Aryl Ketones into Aryl Alkenes, Department of Chemistry , California State University Fullerton , Fullerton, California, 92634, /doi/pdf/10.1080/00397919608004578?needAccess=true. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals.

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